Bioorganic and Medicinal Chemistry Letters p. 625 - 630 (1998)
Update date:2022-08-06
Topics:
Kaiya, Toyo
Aoyama, Shinsuke
Kohda, Kohfuku
Oxidation of seven 1-methylbenzimidazole (MBI) derivatives (with pKa's ranging from 1.6 to 6.0) was carried out with m-chloroperoxybenzoic acid and structures of the products formed were identified. (Condensed benzene moiety-hydroxylated)-2-(m-chlorobenzyloxy)-MBIs and 2-oxo-MBIs were obtained from MBIs with pKa's of more than 5.6 and about 3.3, respectively.
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