A three-step preparation of MAC reagents from malononitrile

DOI: 10.1016/S0040-4039(02)02483-8

Source and publish data:

Tetrahedron Letters p. 73 - 75 (2003)

Update date:2022-08-04

Topics:

Authors:

Nemoto, Hisao

Li, Xinming

Ma, Rujian

Suzuki, Ichiro

Shibuya, Masayuki

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Article abstract of DOI:10.1016/S0040-4039(02)02483-8

An alternative method for the preparation of MAC reagents, H-C(CN)₂O-R, was developed. Using the proposed method, MAC reagents with acyl moiety were synthesized from malononitrile in more than 60% overall yields in three steps.

Full text of DOI:10.1016/S0040-4039(02)02483-8

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