Journal of the Chemical Society. Chemical communications p. 46 - 48 (1990)
Update date:2022-08-04
Topics:
Doyle, Michael P.
Bagheri, Vahid
Claxton, E. Elizabeth
High oxophilicity of metal carbenes formed in rhodium(II) perfluorobutyrate catalysed decomposition of diazocarbonyl compounds allows selective ylide generation from methyl prop-2-yn-1-yl ethers with resulting allene production through the <2,3>-sigmatropic rearrangement.
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