Tetrahedron Letters p. 543 - 546 (1983)
Update date:2022-07-29
Topics:
Porter, Ned A.
Mitchell, John C.
A series of homologous peroxy-bromides is reacted with silver ion in organic solvents.Cyclic peroxide formation occurs along with peroxide transfer to the carbon originally bearing bromine.A preference for five-membered ring peroxonium ion formation is observed in these intramolecular alkylations.
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