Free-radical Addition to Olefins. Part 26.-Kinetics of the Addition of Trifluoromethyl Radicals to Acetylene and Substituted Acetylenes

DOI: 10.1039/F19817700089

Source and publish data:

Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases p. 89 - 100 (1981)

Update date:2022-09-26

Topics:

Authors:

Soueni, Amr El

Tedder, John M.

Walton, John C.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/F19817700089

Absolute Arrhenius parameters have been determined for the addition of trifluoromethyl radicals to acetylene, propyne, but-2-yne, 1,1,1-trifluoropropyne and hexafluorobut-2-yne by a competitive method using the previously determined Arrhenius parameters for the addition of trifluoromethyl radicals to ethylene as standard.

. Both the activation energies and the A-factors are larger than those for the addition of trifluoromethyl radicals to similarly substituted olefins.As a result of these opposing effects the rates of addition are similar.

Full text of DOI:10.1039/F19817700089

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:2-iodoperfluoro-3-methylbut-2-ene

Cas No:685-01-8

R&D Labs maybe for 685-01-8

Suzhou Health Chemicals Co., Ltd.

website:http://www.healthchems.com

Contact:13776257979

Address:No. 338, Jingang Avenue,
Xiamen XM-Innovation Chemical Co., Ltd

Contact:+86-592-3216205

Address:Unit Q, 11/F, No.1 Office Building, Wuyuan Bay Business Center, Huli District, Xiamen City, Fujian Province, P.R.C
HaiNan Periwinkle Pharmaceutical Co.,Ltd.

website:http://www.cchpharm.com/en/index.html

Contact:020-82208978

Address:Gongye road,Wuzhishan city,HaiNan province
Rely Chemicals Ltd.

Contact:+86-518-81061113

Address:No. 8 Lingzhou Road, Lianyungang, Jiangsu, China
WEIFANG RICHEM INTERNATIONAL LTD

Contact:86-536-2222176

Address:weifang,shandong

Relevant to this article

Doi:10.1007/BF00487401
()
Potent Dmt-Tic pharmacophoric δ- and μ-opioid receptor antagonists

Doi:10.1021/jm050377l
(2005)
A CLASS OF NEW SILYLATING REAGENTS. I. A MILD METHOD FOR INTRODUCTION OF THE TERT-BUTYLDIMETHYLSILYL GROUP.

Doi:10.1016/S0040-4039(01)90301-6
(1981)
Non-Peptidic Small-Molecule Inhibitors of the Single-Chain Hepatitis C Virus NS3 Protease/NS4A Cofactor Complex Discovered by Structure-Based NMR Screening

Doi:10.1021/jm0305117
(2004)
Preparation of Fluoro Amines by the Reaction of Aziridines with Hydrogen Fluoride in Pyridine Solution

Doi:10.1021/jo01314a023
(1980)
Reactions of Haloketenes with Allyl Ethers and Thioethers: A New Type of Claisen Rearrangement

Doi:10.1021/jo00154a023
(1983)

Hot Product

About us - Payment - Contact us - Links - Help Center - Disclaimer
SiteMap | Manufacturers | VIP Product | Suppliers | CAS | New CAS | Cas Database | Article Data | Chemical Catalog | Product Name

[Hangzhou]86-0571-87562588,87562578,87562573 Our Legal adviser: Lawyer

Article Doi