Free-radical Addition to Olefins. Part 26.-Kinetics of the Addition of Trifluoromethyl Radicals to Acetylene and Substituted Acetylenes
-
Source and publish data:
Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases p. 89 - 100 (1981)
Update date:2022-09-26
Topics:
-
Authors:
Soueni, Amr El
Tedder, John M.
Walton, John C.
Article abstract of DOI:10.1039/F19817700089
Absolute Arrhenius parameters have been determined for the addition of trifluoromethyl radicals to acetylene, propyne, but-2-yne, 1,1,1-trifluoropropyne and hexafluorobut-2-yne by a competitive method using the previously determined Arrhenius parameters for the addition of trifluoromethyl radicals to ethylene as standard.
. Both the activation energies and the A-factors are larger than those for the addition of trifluoromethyl radicals to similarly substituted olefins.As a result of these opposing effects the rates of addition are similar.
View More
Full text of DOI:10.1039/F19817700089
Products guided by the article
R&D Labs maybe for 685-01-8
-
Jiaxing Carry Bio-Chem Technology Co.,Ltd
website:http://www.carrybiotech.com
Contact:0573-82788958
Address:Add.Fl 3th, Pharm Vally,Kaichuang Rd, Xiuzhou District, Jiaxing, Zhejiang,314031,China
-
Shijiazhuang Haitian Amino Acid Co., Ltd.
Contact:+86-311-88908111
Address:Shijiazhuang Hebei province,China
-
suzhou chukai pharmateach co,.ltd
website:http://www.chukaipharma.com/
Contact:86-512-888125066
Address:Building 3, Wujiang Scientific Innovation Park, 2358 Changan Rd, Wujiang 215200, Jiangsu Province, P. R. China
-
Huayang chemical Co., LTD
Contact:+86-18653358619
Address:zibo
-
MTT Pharma & Bio-technology Co.,Ltd(expird)
Contact:+86-21-58407925
Address:Room2019, Building C, Tomson Center, No.158, Zhang Yang Road, Shanghai, China
- ©2008 LookChem.com,License:ICP NO.:Zhejiang16009103 complaints:service@lookchem.com
-
[Hangzhou]86-0571-87562588,87562578,87562573
Our Legal adviser: Lawyer
