Journal of the Chemical Society. Perkin transactions I p. 2112 - 2116 (1980)
Update date:2022-09-26
Topics:
Boyd, Derek R.
Gadaginamath, Guru S.
Kher, Anil
Malone, John F.
Yagi, Haruhiko
Jerina, Donald M.
Optically pure samples of (+)- and (-)-benzopyrene 7,8-oxide have been synthesized from the separated diastereisomers of trans-8-bromo-7-menthyloxyacetoxy-7,8,9,10-tetrahydrobenzopyrene.The latter separation was effected by short-column chromatography-recrystallisation or high pressure chromatography.The absolute stereochemistry of (+)-trans-8-bromo-7-menthyloxyacetoxy-7,8,9,10-tetrahydrobenzopyrene has been assigned as (7S,8S) by an X-ray crystal structure analysis; this structure has in turn been unequivocally correlated with the stereochemistry of (7S,8R)-(-)-benzopyrene 7,8-oxide and a range of mammalian metabolites.
View MoreSuzhou Howsine Biological Technology Co.,Ltd(expird)
website:http://www.howsine.com
Contact:86-512-67262751
Address:No 3,Weihua Road ,Suzhou Industrial Park ,Jiangsu ,China.
LIAONING DMSO CHEMICALS CO.,LTD.
website:http://www.chinadmso.com
Contact:+86-427-6503033
Address:FLOOR 16, BLOCK A, FINANCIAL SQUARE, XINGLONGTAI DISTRICT, PANJIN CITY, LIAONING P.R. CHINA
Contact:86-516-66656369
Address:The west road of Huaihai, Xuzhou, China
Xi'an Costrong Pharmaceutical Co., Ltd.
Contact:029- 68576496
Address:Room 2004,Shuibao Building,No.190,South Erhuan Rd, Yanta District,Xi'an,Shaan Xi,China
Zhejiang Sucon Silicone Co.,Ltd
Contact:+86-575-88046692
Address:Qisheng Rd., Paojiang Industrial Zone, Shaoxing, Zhejiang, China.
Doi:10.1021/acs.organomet.1c00231
(2021)Doi:10.1016/S0022-328X(00)89076-2
(1978)Doi:10.1021/jo00023a042
(1991)Doi:10.1021/jo01060a023
(1961)Doi:10.1021/jo01325a034
(1979)Doi:10.1016/S0031-9422(00)94599-0
(1978)
