Bulletin of the Academy of Sciences of the USSR Division of Chemical Science p. 2285 - 2291 (1991)
Update date:2022-09-26
Topics:
Chepik, S.D.
Cherstkov, V.F.
Mysov, E.I.
Aerov, A.F.
Galakhov, M.V.
et al.
An unusual electrophilic cyclization of fluorine-containing carbonyl compounds and α-oxides was discovered.Upon the action of SbF5, perfluorinated ketones, diketones, and α-oxides isomerize to oxolanes.This reaction proceeds with the obligatory participation of the terminal CF3 group.
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