
Bulletin of the Chemical Society of Japan p. 2473 - 2480 (1988)
Update date:2022-08-05
Topics:
Tanaka, Mayumi
Oota, Osamu
Hiramatsu, Hideo
Fujiwara, Kazuyoshi
The Knoenvenagel reactions of p-nitrobenzaldehyde (1) with β-keto acids, methylmalonic (2a) and α-methylacetoacetic acids (2b) were carried out in the presence of a tertiary amine such as pyridine.We have isolated the corresponding β-hydroxy intermediate
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