BASISCHE METALLE. XXXVII. ZUR REAKTIVITAET DER ETHYLEN(HYDRIDO)RHODIUM-KOMPLEXE X GEGENUEBER NUCLEOPHILEN: INSERTION VERSUS SUBSTITUTION

DOI: 10.1016/S0022-328X(00)82699-6

Source and publish data:

Journal of Organometallic Chemistry p. 193 - 204 (1982)

Update date:2022-07-30

Topics:

Authors:

Feser, Rainer

Werner, Helmut

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Article abstract of DOI:10.1016/S0022-328X(00)82699-6

The complex BF4 (I) reacts with NaF and NaCN by deprotonation to give C5H5Rh(PMe3)C2H4 but with NaCl, NaBr and NaI the ethylrhodium compounds C5H5RhC2H5(PMe3)X (II-IV) are obtained.The reactions of I with CO and PPrⁱ3 yield t

Full text of DOI:10.1016/S0022-328X(00)82699-6

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Product name:[C₅H₅RhH(CO)P(CH₃)3]⁽¹⁺⁾*BF₄^(1-)=[C₅H₅RhH(CO)P(CH₃)3]BF₄

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