Chemistry of Bicyclohex-1-enes Contrasted with That of 2-Alkylidenecyclopentane-1,3-diyls

DOI: 10.1021/ja00372a019

Source and publish data:

Journal of the American Chemical Society p. 2223 - 2228 (1982)

Update date:2022-07-29

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Authors:

Rule, Mark

Salinaro, Richard F.

Pratt, Dexter R.

Berson, Jerome A.

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Article abstract of DOI:10.1021/ja00372a019

Reaction of 1,1-dibromo-2,6-dimethylhepta-1,5-diene (9) with MeLi in Et2O at -78 deg C results in cyclization to 2,6,6-trimethylbicyclo<3.3.0>hex-1-ene (3), which undergoes and dimerization to 6 and 11, respectively (Scheme II).At 0 deg C,

Full text of DOI:10.1021/ja00372a019

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