Chemistry Letters p. 2051 - 2054 (1992)
Update date:2022-08-05
Topics:
Iwamura, Michiko
Mori, Eiko
Koike, Akemi
Kitagawa, Tomoko
Koga, Noboru
Iwamura, Hiizu
The photochemical reactions of 9-benzyloxytriptycenes in methanol were found to give 2-(9-fluorenyl)benzaldehyde acetals and benzyl 2-(9-fluorenyl)phenyl ketones.Intermediacy of norcaradienes and two kinds of singlet carbenes has been demonstrated by quantum yields, light intensity dependence, competitive reactions, and substituent effects.
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