NEW METHODS AND REAGENTS IN ORGANIC SYNTHESIS. 59. LITHIUM TRIMETHYLSILYLDIAZOMETHANE: A NEW SYNTHON FOR THE PREPARATION OF 5-SUBSTITUTED 1,2,3-THIADIAZOLES

DOI: 10.3987/R-1986-03-0589

Source and publish data:

Heterocycles p. 589 - 592 (1986)

Update date:2022-08-03

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Authors:

Aoyama, Toyohiko

Iwamoto, Yuji

Shioiri, Takayuki

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Lithium trimethylsilyldiazomethane smoothly reacts with thionoesters, dithioesters, and carbon disulfide to give 5-substituted 1,2,3-thiadiazoles.

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