Tetrahedron Letters p. 2177 - 2180 (1985)
Update date:2022-07-30
Topics:
Luo, Fen-Tair
Negishi, Ei-ichi
A Pd-catalyzed allylation of 3-substituted 1-cyclopentenolates with readily obtainable and storable γ-monosubstituted (Z)-allylic acetates in a 1:1 ratio in the presence of 2 mol percent of Pd(PPh3)4 featuring high yields and high stereo- and regioselectivities has been developed and applied to the synthesis of methyl (Z)-jasmonate.
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