Synthetic Communications p. 4035 - 4040 (1997)
Update date:2022-08-04
Topics:
Taherirastgar
Brandsma
A number of acetylenes RCH2C≡CH have been obtained by metallation of the allenes RCH=C=CH2 or mixtures of acetylenes and allenes with n-BuLi in THF-hexane and hydrolysis after allowing the metallated allenes to rearrange at roam temperature or by heating under reflux.
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