Tetrahedron Letters p. 2133 - 2136 (1998)
Update date:2022-08-03
Topics:
Oh, Chang-Young
Kim, Kee-Soo
Ham, Won-Hun
9-Azabicyclo[4.2.1]nonane skeleton 3a was prepared by intramolecular aminocarbonylation of 2a catalyzed by palladium. In three steps 3a was transformed into 8 which had previously been transformed into anatoxin-a, thus completing the formal total synthesis.
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