Sulphone-based Elimination Reactions in Synthesis. Part 1. Moenocinol

DOI: 10.1039/P19830001777

Source and publish data:

Journal of the Chemical Society. Perkin transactions I p. 1777 - 1781 (1983)

Update date:2022-08-05

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Authors:

Kocienski, Philip

Todd, Michael

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Article abstract of DOI:10.1039/P19830001777

The fluoride-induced elimination of a β-phenylsulphonylsilane and the reductive elimination of a β-oxysulphone are key olefin-forming reactions in a synthesis of moenocinol <(2Z,6E,13E)-3,8,8,14,18-pentamethyl-11-methylenenonadeca-2,6,13,17-tetraen-1-ol>.

Full text of DOI:10.1039/P19830001777

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