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Diels-Alder Reactions of Cycloalkenones. 12. Reaction of trans-Δ1,2-3-Octalone with (E)-Piperylene

DOI: 10.1021/jo00242a015

Source and publish data:

Journal of Organic Chemistry p. 1424 - 1426 (1988)

Update date:2022-08-05

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Authors:

Angell, E. CharlesAngell, E. Charles

Fringuelli, FrancescoFringuelli, Francesco

Pizzo, FerdinandoPizzo, Ferdinando

Taticchi, AldoTaticchi, Aldo

Wenkert, ErnestWenkert, Ernest

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Article abstract of DOI:10.1021/jo00242a015

The Diels-Alder reaction of (E)-piperylene with trans-Δ1,2-3-octalone under aluminum chloride catalysis is described and structure analysis of the adducts by NMR spectroscopy is presented.The diastereofacial selectivity of the reaction is discu

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Full text of DOI:10.1021/jo00242a015

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