Potassium dihydrogen trifluoride: a novel fluorinating reagent for ring-opening of epoxides

DOI: 10.1016/0022-1139(94)03175-Y

Source and publish data:

Journal of Fluorine Chemistry p. 1 - 4 (1995)

Update date:2022-08-03

Topics:

Authors:

Tamura, Masanori

Shibakami, Motonari

Arimura, Takashi

Kurosawa, Shigeru

Sekiya, Akira

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Article abstract of DOI:10.1016/0022-1139(94)03175-Y

It has been found that potassium dihydrogen trifluoride is an efficient and easy-to-handle solid reagent for the ring-opening reaction of epoxides giving fluorhydrins regio- and stereo-selectively.The reaction proceeds via cis-addition of HF to the epoxide. - Keywords: Potassium dihydrogen trifluoride; Fluorinating reagent; Ring-opening; Epoxides; Fluorohydrin synthesis

Full text of DOI:10.1016/0022-1139(94)03175-Y

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