Journal of Fluorine Chemistry p. 1 - 4 (1995)
Update date:2022-08-03
Topics:
Tamura, Masanori
Shibakami, Motonari
Arimura, Takashi
Kurosawa, Shigeru
Sekiya, Akira
It has been found that potassium dihydrogen trifluoride is an efficient and easy-to-handle solid reagent for the ring-opening reaction of epoxides giving fluorhydrins regio- and stereo-selectively.The reaction proceeds via cis-addition of HF to the epoxide. - Keywords: Potassium dihydrogen trifluoride; Fluorinating reagent; Ring-opening; Epoxides; Fluorohydrin synthesis
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