The Kinetics of the Thermal Deammonation of X2 in the Solid State

Article abstract of DOI:10.1246/bcsj.53.807

The isothermal kinetics of the substitution reaction of an ammonia with an outer-sphere anion was studied in the solid state; X2(s) -> X(s) + NH3(g) (X=Cl, Br, I).The kinetic parameters provided some evidence for a dissociative mechanism.