Photosubstitution Reactions of : Some Evidence for an α-Elimination Mechanism

DOI: 10.1039/DT9810000314

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 314 - 316 (1981)

Update date:2022-08-04

Topics:

Authors:

Costa, Silvia M. B.

Dias, Alberto R.

Pina, Fernando J. S.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/DT9810000314

Irradiation of in the presence of L led to the isolation of the following products: , (when L = PMe2Ph), and , (when L = py or MeCN).An α-elimination mechanism is proposed for these reactions.In a study of the related thermal reactions the products were the same as in the photochemical reactions for L = PMe2Ph; for L = py the sole product isolated was ; and no reaction was observed with L = MeCN.

Full text of DOI:10.1039/DT9810000314

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:bis(η-cyclopentadienyl)(dimethylphenylphosphine)methyltungstenhexafluorophosphate

Cas No:71531-98-1

R&D Labs maybe for 71531-98-1

Shaanxi Sinuote Biotech Co.,Ltd

Contact:+86-29-68859685

Address:No 18,Taiyuan Road ,Xi'an city ,China
Accela ChemBio Inc.

Contact:1-858-6993322

Address:9883 Pacific Heights Blvd., Suite H, San Diego
Nanjing Legend Pharmaceutical & Chemical Co., Ltd.

Contact:+86-25-83767696

Address:14-7 Zhongshan Lu Guluo District, Nanjing
LIANYUNGANG YC FINE CHEMICAL CO., LTD

Contact:+86-518-858 99188

Address:Shangdong Modern Bldg, South Greenpark Road, Lianyungang, Jiangsu Pro. China
Eastar Chemical Corporation

website:http://www.eastarchem.com/

Contact:1-800-898-2436

Address:1215 K Street, STE 1700

Relevant to this article

Glycosylated foldamers to probe the carbohydrate-carbohydrate interaction

Doi:10.1021/ja0614565
(2006)
Doi:10.1021/jo01056a032
(1962)
Synthesis of glucuronic, mannuronic, and galacturonic acid-derived imidazoles as inhibitors of bovine liver β-glucuronidase

Doi:10.1002/hlca.200690137
(2006)
Doi:10.1007/s004170100346
(1899)
Doi:10.1002/hlca.19500330440
(1950)
An N,N′-chelated phosphenium cation supported by a β-diketiminate ligand

Doi:10.1039/b607549e
(2006)

Article Doi