Photosubstitution Reactions of : Some Evidence for an α-Elimination Mechanism

DOI: 10.1039/DT9810000314

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 314 - 316 (1981)

Update date:2022-08-04

Topics:

Authors:

Costa, Silvia M. B.

Dias, Alberto R.

Pina, Fernando J. S.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/DT9810000314

Irradiation of in the presence of L led to the isolation of the following products: , (when L = PMe2Ph), and , (when L = py or MeCN).An α-elimination mechanism is proposed for these reactions.In a study of the related thermal reactions the products were the same as in the photochemical reactions for L = PMe2Ph; for L = py the sole product isolated was ; and no reaction was observed with L = MeCN.

Full text of DOI:10.1039/DT9810000314

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:bis(η-cyclopentadienyl)(dimethylphenylphosphine)methyltungstenhexafluorophosphate

Cas No:71531-98-1

R&D Labs maybe for 71531-98-1

Shanghai Korey Pharm Co.,Ltd.(expird)

Contact:021-61840961 021-61840962

Address:No.157,Zhuguang Rd, Qingpu, Shanghai, China
Zhejiang Haizhou Pharmaceutical Co., Ltd.

website:https://www.haizhoupharma.com/

Contact:+86-576-88221016

Address:No. 19, Donghai 5th Avenue, Yanhai Industrial Zone, Linhai, Zhejiang, China
Hangzhou yi lu biont technology Co., LTD

Contact:+86-571-88152630

Address:Hangzhoushi HuafengRoad Yicheng3Building1001room.
SHANDONG ZHANHUA YONGHAO PHARMACEUTICAL TECH.CO.,LTD

Contact:+86-576-88685096

Address:GENGJU VILLAGE NORTH ONE KILOMETER,ZHANHUA DISTRICT,BINZHOU CITY,SHANDONG PROVINCE,CHINA.
Jinan Jiaquan Chemical Co.,Ltd

Contact:+86-531-62318366

Address:Room 502 of Yidonghuayuan No.601 Huaxin Road Licheng District Jinan China

Relevant to this article

Glycosylated foldamers to probe the carbohydrate-carbohydrate interaction

Doi:10.1021/ja0614565
(2006)
Doi:10.1021/jo01056a032
(1962)
Synthesis of glucuronic, mannuronic, and galacturonic acid-derived imidazoles as inhibitors of bovine liver β-glucuronidase

Doi:10.1002/hlca.200690137
(2006)
Doi:10.1007/s004170100346
(1899)
Doi:10.1002/hlca.19500330440
(1950)
An N,N′-chelated phosphenium cation supported by a β-diketiminate ligand

Doi:10.1039/b607549e
(2006)

Article Doi