Photosubstitution Reactions of : Some Evidence for an α-Elimination Mechanism

DOI: 10.1039/DT9810000314

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 314 - 316 (1981)

Update date:2022-08-04

Topics:

Authors:

Costa, Silvia M. B.

Dias, Alberto R.

Pina, Fernando J. S.

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Article abstract of DOI:10.1039/DT9810000314

Irradiation of in the presence of L led to the isolation of the following products: , (when L = PMe2Ph), and , (when L = py or MeCN).An α-elimination mechanism is proposed for these reactions.In a study of the related thermal reactions the products were the same as in the photochemical reactions for L = PMe2Ph; for L = py the sole product isolated was ; and no reaction was observed with L = MeCN.

Full text of DOI:10.1039/DT9810000314

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