Reactions of Ruthenium Triphenylphosphine Complexes with Diazadienes. Part 1. Reactions of and and Disproportionation of a Hydridochloro-complex

DOI: 10.1039/DT9800000539

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 539 - 544 (1980)

Update date:2022-08-03

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Authors:

Chaudret, Bruno

Poilblanc, Rene

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Article abstract of DOI:10.1039/DT9800000539

The reactions between and half or one equivalent of a diazadiene (dad) give respectively molecular and ionic binuclear triply chloro-bridged complexes, and Cl which can also be obtained as its BPh4 salt.The compound reacts with diazadienes to produce , which disproportionates in polar solvents to give a hydrido- and a dichloro-compound and reacts with water to give a chlorodihydroxo-bridged hydrido-species, .

Full text of DOI:10.1039/DT9800000539

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