Tetrahedron p. 2029 - 2034 (1987)
Update date:2022-08-02
Topics:
Redlich, Hartmut
Bruns, Wilfried
Francke, Wittko
Schurig, Volker
Payne, Thomas L.
Vite, Jean Pierre
The synthesis of both enantiomers of endo-7-ethyl-5-methyl-6,8-dioxabicyclo[3.2.l]octana (endo-brevicomin, 12 and 12a) starting froni D-ri-bose is described. Key interinediate is the open chain derivative 7, a chiral building unit easily available from ca
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