Tetrahedron Letters p. 3183 - 3186 (1984)
Update date:2022-07-31
Topics:
Monjoint, Pierre
Ruasse, Marie-Francoise
Kinetics of the reaction of 1-tosyl-3-methyl-imidazolium chloride with various amines were measured to examine the nature of sulfonyl transfer in enzymatic reactions.The activations parameters and the value of the Broensted exponent, β=0.48, are consistent with a small degree of bonding between the entering amine and the sulfur atom in the transition state.Similarities in the nucleophilic behavior of sulfonyl and carbonyl groups are detected.
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Doi:10.1016/S0040-4020(00)01094-2
(2001)Doi:10.1515/znb-2004-0403
(2004)Doi:10.1016/j.tetlet.2004.04.116
(2004)Doi:10.1039/b312930f
(2004)Doi:10.1016/S0957-4166(03)00481-6
(2003)Doi:10.1246/cl.1979.1279
(1979)
