Synthesis and some reactions of tris (pentafluorophenyl) antimony compounds

Article abstract of DOI:10.1016/S0277-5387(00)84497-6

(C₆F₅)₃Sb has been found to react with interhalogens and halo-pseudohalogens, IX(X = Cl, Br, N₃ and NCO), pseudohalogen (SCN), and elemental sulphur to give oxidative addition products (I-VI). (C₆F₅)₃SbS(VI) may also be prepared by the reaction of (C₆F₅)₃SbCl₂ with H₂S. Metathetical reactions of (C₆F₅)₃SbCl₂ with appropriate metallic salts yield covalent pentacoordinate disubstituted products (V, VII-XII) of the general formula, (C₆F₅)₃SbY₂ (Y = NCS, NCO, -ONCMe₂, -ONCMePh -NCO(CH₂)₂CO and p-NO₂C₆H₄OCO). Treatment of (C₆F₅)₃SbCl₂ with aqueous NaN₃ gives the binuclear oxo-bridge compound, [(C₆F₅)₃SbOSb(C₆F₅)₃](N₃)₂·(III) and (IV) are also accessible by displacement reaction of (I) or (II) with the corresponding metallic salt. Molecular weight, conductance measurements, and IR spectra on the new organoantimony(V) derivatives have been obtained. Reductive cleavage reactions of (C₆F₅)₃SbS with hexaaryldileads, Ar₆Pb₂(Ar = Phenyl, p-tolyl) produce (C₆F₅)₃Sb and the corresponding bis(triaryllead) sulphide but treatment of (C₆F₅)₃SbX₂(X = NCO, Cl) with Ar₆Pb₂ gave Ar₄Pb and Ar₂PbX₂ together with (C₆F₅)₃Sb. (C₆F₅)₃SbCl₂ and bis(triorganotin)sulphides undergo exchange of anionic groups.