Chemistry Letters p. 741 - 744 (1981)
Update date:2022-08-05
Topics:
Mizuno, Kazuhiko
Ogawa, Jun
Otsuji, Yoshio
The cyclopropane ring of arylcyclopropanes is oxidatively cleaved by irradiation in polar solvents containing nucleophiles such as alcohols, water, and sodium cyanide in the presence of electron-acceptor such as 1,4-dicyanobenzene and 1-cyanonaphthalene, giving nucleophile-incorporated products.This photoreaction proceeds via an electron-transfer from the cyclopropanes to the excited electron-acceptors, and the cation radicals of arylcyclopropanes are involved as key intermediates.
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