Journal of Organic Chemistry p. 715 - 719 (1980)
Update date:2022-08-05
Topics:
Seuron, Patrick
Solladie, Guy
Optically active trans-cyclooctene was obtained by Hofmann elimination of trimethylcyclooctyl ammonium hydroxide in new cholesteric liquid crystals.The extent of asymmetric induction rose 7 percent.Enantiomeric equilibration of racemic trans-cyclooctene in cholesteric medium, at 180 deg C, leads to a 2 percent enantiomeric excess.These asymmetric induction results are interpreted in terms of solute-solvent interactions enhanced by the local ordering of the mesophase.
View MoreContact:
Address:308# dongwu avenue dongxihu district wuhan city
Tianjin Bright Future Technology Co., Ltd
Contact:0086-22-58016666
Address:NO.136 DongTeng Lake Street Tianjin Economic and Technology Development Area,Tainjin,China
Contact:+86-27-85733560
Address:NO.308,QINGNIAN RD.,WUHAN,CHINA
Shanghai Coupling Pharmaceutical R&D Co., Ltd.(expird)
Contact:+86 021 50106671
Address:403 Room No.4 Buiding, No. 526 Ruiqing Road, Shanghai Zhangjiang Hi-Tech Park
Hunan Dinuo Pharmaceutical Co.,Ltd.
Contact:86-731-88280100*8561
Address:Bio-pharmaceutical industrial park, Liuyang, Hunan, China
Doi:10.1002/jms.543
(2003)Doi:10.1016/j.bmcl.2004.04.086
(2004)Doi:10.1246/cl.1979.1077
(1979)Doi:10.1039/d0ra03520c
(2020)Doi:10.1139/v66-282
(1966)Doi:10.1023/B:RUCB.0000011870.91892.43
(2003)
