Single Electron Reduction of Tetracyanoquinodimethane, TCNQ and Phenazine and Two Electron Reduction of TCNQ by Organo-iron Electron Reservoir Complexes

DOI: 10.1039/c39850000450

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 450 - 452 (1985)

Update date:2022-08-05

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Authors:

Desbois, Marie-Helene

Michaud, Pascal

Astruc, Didier

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Article abstract of DOI:10.1039/c39850000450

cp(C6Me6)Fe(I), (1), (cp=C5H5) reacts with one equivalent of phenazine and tetracyanoquinodimethane, TCNQ, to give the single electron transfer salts cp(C6Me6)Fe(1+), phenazine(1-), (2), and cp(C6Me6)Fe(1+), TCNQ(1-), (3), whereas addition of TCNQ to 2 eq

Full text of DOI:10.1039/c39850000450

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