
Organic Magnetic Resonance p. 573 - 575 (1983)
Update date:2022-08-05
Topics:
Julia, S.
Ginebreda, A.
Sala, P.
Sancho, M.
Annunziata, R.
Cozzi, F.
The NMR variable temperature behaviour of a series of N-aryl-N-benzyl alkyl carbamates was investigated.The barrier to rotation about the N-aryl bond was determined for all the compounds studied.The values obtained, which are in good agreement with those found for structurally related N-aryl-N-benzylamides, are in the range ΔG=60.7-89.6 kJ mol-1.For some carbamates another conformational phenomenon has been observed, namely the hindered rotation about the carbonyl carbon-nitrogen bond, with a barrier to rotation corresponding to reported values for similar systems.
View MoreChangsha Yihai Chemical Technology Co.,ltd
website:http://www.cs-yihai.com/
Contact:0731- 85620465
Address:Room 23005, unit 2, the northern building of Xiangsong international building , NO.259 Shaoshan Road , Changsha , Hunan, China.(mainland)
ShangHai Ruiyi Medical Technology Co.,Ltd.
Contact:+86-21-54718086
Address:No951 Jianchuan RD,Minhang District
Suzhou Jingye Medicine & Chemical Co., Ltd
Contact:+86-512-66658588
Address:No. 88, Sanlian Street, Jinfeng Road, Suzhou New District, Jiangsu Province, P. R. China
SHANGHAI RC CHEMICALS CO.,LTD.
website:http://www.rcc.net.cn
Contact:+86-21-50322175
Address:Rm1415 Yinqiao Masion No.58 Jinxin Road Pudong Shanghai China
Contact:(86) 731 88718666
Address:Room 1222, Unit 4, Building B, Shangcheng, No.47, Kaiyuan East Road.
Doi:10.1016/S0020-1693(00)81555-8
(1988)Doi:10.1016/0008-6215(91)80099-9
(1991)Doi:10.1039/a606699b
(1997)Doi:10.1039/DT9800000776
(1980)Doi:10.1021/jo01297a005
(1980)Doi:10.1039/b402616k
(2004)