Degenerate Cyclopropylcarbinyl Cation Rearrangement in 2-Bicycloalkyl Cations

DOI: 10.1021/jo01294a010

Source and publish data:

Journal of Organic Chemistry p. 965 - 969 (1980)

Update date:2022-08-02

Topics:

Authors:

Olah, George A.

Prakash, G.K.Surya

Rawdah, Tarik N.

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Article abstract of DOI:10.1021/jo01294a010

The ionization of bicycloalkan-2-ols in superacids (SbF5, FSO3H, FSO3H-SbF5) to the corresponding carbocations has been investigated by 13C NMR spectroscopy over the temperature range of 0 to -140 deg C.The bicyclic system, n = 4, gave a degenerate

Full text of DOI:10.1021/jo01294a010

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