Degenerate Cyclopropylcarbinyl Cation Rearrangement in 2-Bicycloalkyl Cations

DOI: 10.1021/jo01294a010

Source and publish data:

Journal of Organic Chemistry p. 965 - 969 (1980)

Update date:2022-08-02

Topics:

Authors:

Olah, George A.

Prakash, G.K.Surya

Rawdah, Tarik N.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo01294a010

The ionization of bicycloalkan-2-ols in superacids (SbF5, FSO3H, FSO3H-SbF5) to the corresponding carbocations has been investigated by 13C NMR spectroscopy over the temperature range of 0 to -140 deg C.The bicyclic system, n = 4, gave a degenerate

Full text of DOI:10.1021/jo01294a010

Products guided by the article

Product name:C₁₃H₁₅⁽¹⁺⁾

Cas No:72610-50-5

R&D Labs maybe for 72610-50-5

Hebei Think-Do Environment Co., Ltd

website:http://www.thinkdo-environment.com

Contact:0311-86510809-

Address:No 6, Shilian Middle Street, Circular Chemical Industry Park
Tianjin Jiuri New Materials Co., Ltd.

Contact:+86-22-58889220

Address:C-5/6, Vison Hill, No.1 Gonghua Road, Huayuan Hi-tech Park, Tianjin, China.
Nanjing Duly Biotech Co., Ltd

website:http://www.dulynet.com/

Contact:025-84699383 -8003

Address:Room 503, Building 2, Chuangxinhui, No. 61 Wenjing Road, High-tech Development Zone, Pukou District, Nanjing City, Jiangsu Province Nanjing, Jiangsu
AURORA CHEMICAL CO., LTD

Contact:86-532-68629711 13780605697

Address:NO 220 YANAN 3 ROAD,(POST ADMINISTRATION BUILDING),QINGDAO,CHINA
Wuhan Kemi-Works Chemical Co., Ltd

website:http://www.kemiworks.com

Contact:86-27-85736489

Address:Rm. 1503, No. 164, Jianghan North Rd., Wuhan, 430022 China

Relevant to this article

Vinylation of α-Aminoazoles with Triethylamine: A General Strategy to Construct Azolo[1,5-a]pyrimidines with a Nonsubstituted Ethylidene Fragment

Doi:10.1021/acs.orglett.1c00571
(2021)
Doi:10.1055/s-1979-28886
(1979)
Doi:10.1021/jo01059a027
(1962)
Borane Reduction of Uracil Derivatives

Doi:10.1021/jo00200a050
(1984)
Doi:10.1039/jr9630002417
(1963)
ASYMMETRIC HYDROGENATION OF N-(α-KETOACYL)-α-AMINO ESTERS

Doi:10.1246/cl.1986.737
(1986)

Article Doi