Synthesis of Alkyl Hydroperoxides by Hydroperoxymercuriation and Reduction

DOI: 10.1039/c39920000926

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 926 - 927 (1992)

Update date:2022-08-05

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Authors:

Bloodworth, A. J.

Cooksey, Christhopher J.

Korkodilos, Despoina

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Article abstract of DOI:10.1039/c39920000926

Alkyl hydroperoxides, R1R2C(OOH)CH2R3, have been prepared from 30percent hydrogen peroxide by hydroperoxymercuriation of the corresponding alkenes, R1R2C=CHR3, followed by addition to 2-methoxypropene, reductive demercuriation with basic sodium borohydride and deprotection of the resultant 2-methoxyprop-2-yl derivatives, R1R2C(OOCMe2OMe)CH2R3, with aqueous acetic acid.

Full text of DOI:10.1039/c39920000926

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