Journal of Organometallic Chemistry p. 195 - 204 (1980)
Update date:2022-08-05
Topics:
Schenk, Wolfdieter A.
cis- and trans-tetracarbonyltungsten complexes (R3P)(R'3E)W(CO)4 (R3P, R'3E=i-Pr3P, Ph2-i-PrP, Ph3P, Ph2HP, (Me2N)3P, Ph(i-PrO)2P, (i-PrO)3P, (PhO)3P, Ph3As, Ph3Sb) are obtained from the chlorotetracarbonyltungstates <(R3P)W(CO)4Cl>- by several different routes.A cis-trans equilibrium is attained at 20-80 deg C with the trans isomer being thermodynamically more stable in nearly all cases.The cis-trans isomerisation of the phosphine-arsine and phosphine-stibine complexes is shown by ligand exchange experiments to occur via dissociation of the arsine and stibine ligand, respectively.The bis(phosphine) complexes, however, isomerise intramolecularly without bond cleavage.
Shijiazhuang City Xiehe Pharmaceutical Co., Ltd
Contact:+86-311-80817929
Address:Shangzhuang,Shijiazhuang,China
Contact:+86-15850770348
Address:51 OF XIANGFANGCUN ROAD, Nanjing 210002, China
Rizhao Lanxing Chemical Indusrial Co.,Ltd
Contact:86-633-2616708
Address:NO.15 West road Shenglan, Lanshan district, Rizhao City
SHAANXI TOP PHARM CHEMICAL CO.LTD
Contact:+86-029-85733403
Address:No.108 ,west sector,south er huan,xi'an,china
Ji'an Kexin Trade Co., Ltd.(expird)
Contact:86-0796-8187704 18507063190
Address:ji'an jiangxi
Doi:10.1021/jm00178a020
(1980)Doi:10.1007/BF00846293
()Doi:10.1039/c5ra20524g
(2016)Doi:10.1016/S0022-328X(00)83511-1
(1980)Doi:10.1016/j.ica.2013.11.014
(2014)Doi:10.1002/hlca.200690058
(2006)
