Journal of the Chemical Society. Perkin transactions I p. 3043 - 3046 (1991)
Update date:2022-07-31
Topics:
Tabuchi, Toshihiko
Nojima, Masatomo
Kusabayashi, Shigekazu
The ozonolysis of vinyl ethers 1a, b in the presence of adamantane-2-thione 4a and bicyclo<3.3.1>nonan-9-thione 4b gave in each case the corresponding thioozonides 5a-c in moderate yields, whilst ozonolysis of a mixture of vinyl ethers 1a-d and thiobenzophenone derivatives 4f-h gave the corresponding thione S-oxides 8f-h in isolated yields of 10-40percent, together with the benzophenones 7f-h. 3,3-Dimethyl-1,2-dioxirane, generated in situ from the reaction of acetone and 'oxone' (2KHSO5-KHSO4-K2SO4), transferred an oxygen atom to compounds 4a, f, g, i providing the thione S-oxides 8a, f, g, i in 29-97 percent yield.
View MoreContact:+86-22-26358246
Address:601-4-20, Fujiayuan, Tiantai Road, Hebei District, Tianjin, China
BrightGene Bio-Medical Technology Co., Ltd.
website:https://en.bright-gene.com/
Contact:+86-512-62551801
Address:Building C25 - C31, No. 218 Xinghu Road, Suzhou Industrial Park, Suzhou, Jiangsu, China.
Contact:0550-7041128 0550-7090578
Address:Wangdian Street,Xinjie Town
Contact:+86-371-55981030
Address:Room 1571, Macalline Soho, No.1, Shangdu Road, Zhengzhou, Henan
Shandong Xiangde Biotechnology Co., Ltd
Contact:+86 -15066639877
Address:Sanba street
Doi:10.1021/cs400983y
(2014)Doi:10.1021/acs.joc.8b01479
(2018)Doi:10.1021/jo00078a046
(1993)Doi:10.1021/ja00072a063
(1993)Doi:10.1039/c3dt52373j
(2014)Doi:10.1002/chem.201304215
(2014)
