Tetrahedron Letters p. 3923 - 3926 (1994)
Update date:2022-08-02
Topics:
Drouet
Thomas
Legoy
The synthetic potential of soybean lipoxygenase 1 (LOX 1) for the synthesis of 13(S) hydroperoxy-9(Z),11(E)-octadecadienoic acid is investigated in a biphasic medium (octane; borate buffer, pH 9.6). Improvement of the reaction yield (compared to an aqueous system) is observed at very high concentration (20-40 g/L). The regioselectivity of the reaction is not affected by the presence of the organic phase.
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