Reactions of 1,1-Diarylethylenes and 1,1-Diarylimines with CF3OF

DOI: 10.1021/jo01296a013

Source and publish data:

Journal of Organic Chemistry p. 1409 - 1413 (1980)

Update date:2022-08-05

Topics:

Authors:

Patrick, Timothy B.

Cantrell, Gary L.

Inga, Sandra M.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo01296a013

1,1-Diphenylethylene (1) reacts with CF3OF to give products 2-6 in a cationic process. 9-Ethylidenefluorene reacts with CF3OF to yield 8 and 10.Amitriptyline (12) furnished a difluoro adduct (13) in low yield.Benzophenone oxime (14) gave a Beckmann rearrangement product on reaction with CF3OF.Fluorenone anil (15) produced mainly fluorenone from reaction with CF3OF.Diazepam (16) gave a 1:1 adduct (18) with CF3OF.The adduct 18 reacted further to give an oxidation product (17).

Full text of DOI:10.1021/jo01296a013

Products guided by the article

Product name:7-Chloro-4-fluoro-1-methyl-5-phenyl-5-trifluoromethoxy-1,3,4,5-tetrahydro-benzo[e][1,4]diazepin-2-one

Cas No:73048-41-6

R&D Labs maybe for 73048-41-6

Shanghai UCHEM Inc.

Contact:+86-21-56338808

Address:799 Dunhuang Road, Putuo
Tianjin Anda North Industrial & Business Co.Ltd.

Contact:86-22-24999306

Address:No.11 Erwei Road,Dongli Development Area,Tianjin,China
hangzhou verychem science and technology co.ltd

website:http://www.verypharm.com

Contact:+86-571-88162785; 88162786

Address:F1502, 753 Shenhua road, Hangzhou, China
Shanghai shibo Chemical Co., Ltd

Contact:+86-021-60753516

Address:688 Qiushi Road, Jinshan High-tech Park, Shanghai, China,201512
Alway Chem, China

website:http://www.alwaychem.com

Contact:+86-532-8586-4000, 8586-5000

Address:NO.51, TAIPING ROAD, QINGDAO, CHINA. 266001

Relevant to this article

Dialkylamino- and alkoxytrialkylstannanes as reagent for synthesis of organoboryl (trialkylsilyl) ketenes

Doi:10.1007/BF00717355
(1994)
Benzylidene acetal fragmentation route to 6-deoxy sugars: Direct reductive cleavage in the presence of ether protecting groups, permitting the efficient, highly stereocontrolled synthesis of β-D-rhamnosides from D-mannosyl glycosyl donors

Doi:10.1021/ja048070j
(2004)
A new synthesis of α,α-disubstituted carbonyl compounds from carbonyl compounds with one-carbon homologation

Doi:10.1016/j.tetlet.2004.04.154
(2004)
Syntheses and DNA-binding studies of a series of unsymmetrical cyanine dyes: Structural influence on the degree of minor groove binding to natural DNA

Doi:10.1016/j.bmc.2004.02.006
(2004)
Functionalization of 2-Methyl-3-o-tolyl-4(3H)-quinazolinone and Related Compounds through Carbanion Reactions at the 2-Methyl Group

Doi:10.1021/jo01299a027
(1980)
Conversion of Benzo- and Naphthonorcaradien-7-yl to Benzo- and Naphthotropyl Radicals

Doi:10.1021/ja00522a040
(1980)

Article Doi