Journal of Organic Chemistry p. 1409 - 1413 (1980)
Update date:2022-08-05
Topics:
Patrick, Timothy B.
Cantrell, Gary L.
Inga, Sandra M.
1,1-Diphenylethylene (1) reacts with CF3OF to give products 2-6 in a cationic process. 9-Ethylidenefluorene reacts with CF3OF to yield 8 and 10.Amitriptyline (12) furnished a difluoro adduct (13) in low yield.Benzophenone oxime (14) gave a Beckmann rearrangement product on reaction with CF3OF.Fluorenone anil (15) produced mainly fluorenone from reaction with CF3OF.Diazepam (16) gave a 1:1 adduct (18) with CF3OF.The adduct 18 reacted further to give an oxidation product (17).
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Doi:10.1007/BF00717355
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(1980)
