Reactions of 1,1-Diarylethylenes and 1,1-Diarylimines with CF3OF

DOI: 10.1021/jo01296a013

Source and publish data:

Journal of Organic Chemistry p. 1409 - 1413 (1980)

Update date:2022-08-05

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Authors:

Patrick, Timothy B.

Cantrell, Gary L.

Inga, Sandra M.

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Article abstract of DOI:10.1021/jo01296a013

1,1-Diphenylethylene (1) reacts with CF3OF to give products 2-6 in a cationic process. 9-Ethylidenefluorene reacts with CF3OF to yield 8 and 10.Amitriptyline (12) furnished a difluoro adduct (13) in low yield.Benzophenone oxime (14) gave a Beckmann rearrangement product on reaction with CF3OF.Fluorenone anil (15) produced mainly fluorenone from reaction with CF3OF.Diazepam (16) gave a 1:1 adduct (18) with CF3OF.The adduct 18 reacted further to give an oxidation product (17).

Full text of DOI:10.1021/jo01296a013

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