Orthoacrylate Claisen Rearrangement. An Approach to Aliphatic α-Methylene Esters

DOI: 10.1021/jo01299a008

Source and publish data:

Journal of Organic Chemistry p. 2080 - 2083 (1980)

Update date:2022-08-05

Topics: Starting Material Product Utility

Authors:

Saucy, Gabriel

Cohen, Noal

Banner, Bruce L.

Trullinger, Daniel P.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo01299a008

Treatment of vinyl carbinols 1a,b with triethyl orthoacrylate (2) and excess propionic acid in refluxing toluene gives the α-propionoxymethyl esters 8a,b as major products along with minor amounts of the α-ethoxymethyl esters 7a,b.Similar treatment of eth

Full text of DOI:10.1021/jo01299a008

Products guided by the article

Product name:rac-Diethyl 3-(4-Methyl-1,2-pentadien-1-yl)-5-(2-methylpropylidene)-1⁽⁶⁾-cyclohexen-1,3-dicarboxylate

Cas No:73262-64-3

R&D Labs maybe for 73262-64-3

Nanjing Chemzam Pharmtech Co., Ltd.

Contact:+86-25-86462165,+86-13915979898

Address:C5-1，6 Maiyue Road，Maigaoqiao，Nanjing，Jiangsu，China
Shanghai Yingrui Biopharma Co., Ltd

Contact:021-3358 8661*8003

Address:shanghai
Laizhou City Laiyu Chemical CO.,Ltd

Contact:+86-535-2719337/2719339

Address:Chenggang road zhuyou laizhou City Shangdong China
Hangzhou Bayee Chemical Co.,Ltd.

Contact:+86-571-86990109

Address:No.380, Jiangnan Auenue, Binjiang District, Hangzhou, China
shanghai payne pharm co.,ltd.

Contact:+86-021-58123769

Address:No.780 of Cailun Road,Zhangjiang Hi-tech Park,Pudong,Shanghai

Relevant to this article

Derivatives of the potent angiotensin converting enzyme inhibotor 5(S)-benzamido-4-oxo-6-phenylhexanoyl-L-proline: Effect of changes at positions 2 and 5 of the hexanoic acid portion

Doi:10.1021/jm00353a005
(1982)
Synthesis of Tetranuclear Iron-Sulphur Protein Analogues with Tetrathiol Ligands attached to Macrocycles which provide Intramolecular Hydrophobic Domains

Doi:10.1039/DT9900003375
(1990)
FULVENE-PLATINUM COMPLEXES: X-RAY CRYSTAL STRUCTURE OF 2-C5H4CPh2)(PPh3)2>

Doi:10.1016/S0022-328X(00)89072-5
(1982)
Visible light-mediated atom transfer radical addition via oxidative and reductive quenching of photocatalysts

Doi:10.1021/ja300798k
(2012)
Conversion of (Z)-1,4-dihydroxyalk-2-enes into 2,5-dihydrofurans and of alkane-1,4-diols into tetrahydrofurans via acid-catalysed cyclisation of the monoisoureas formed by their copper(I)-mediated reactions with dicyclohexylcarbodiimide

Doi:10.1039/b203389p
(2002)
DECARBOXYLATION OF SODIUM GLYCIDATES: A CONVENIENT METHOD FOR THE SYNTHESIS OF α-ACETOXYKETONES, α-DIKETONES, AND α-KETOESTERS

Doi:10.1246/cl.1982.879
(1982)

Article Doi