Orthoacrylate Claisen Rearrangement. An Approach to Aliphatic α-Methylene Esters

DOI: 10.1021/jo01299a008

Source and publish data:

Journal of Organic Chemistry p. 2080 - 2083 (1980)

Update date:2022-08-05

Topics: Starting Material Product Utility

Authors:

Saucy, Gabriel

Cohen, Noal

Banner, Bruce L.

Trullinger, Daniel P.

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Article abstract of DOI:10.1021/jo01299a008

Treatment of vinyl carbinols 1a,b with triethyl orthoacrylate (2) and excess propionic acid in refluxing toluene gives the α-propionoxymethyl esters 8a,b as major products along with minor amounts of the α-ethoxymethyl esters 7a,b.Similar treatment of eth

Full text of DOI:10.1021/jo01299a008

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