Stereospecific Synthesis of trans-1,3-Disubstituted-1,2,3,4-tetrahydro-β-carbolines

DOI: 10.1021/jo00314a035

Source and publish data:

Journal of Organic Chemistry p. 164 - 168 (1981)

Update date:2022-08-03

Topics:

Authors:

Ungemach, F.

DiPierro, M.

Weber, R.

Cook, J. M.

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Article abstract of DOI:10.1021/jo00314a035

The Pictet-Spengler condensation of N_b-benzyltryptophan methyl ester 1a with aldehydes 2a-d has been found to occur in a stereospcific fashion.Stereoelectronic (antiperiplanar) attack of the 2,3-indole double bond on the intermediate benziminiu

Full text of DOI:10.1021/jo00314a035

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