Journal of Organometallic Chemistry p. 265 - 276 (1980)
Update date:2022-08-02
Topics:
Abicht, Hans-Peter
Issleib, Kurt
The (o-lithiobenzyl)diorganophosphines o-LiC6H4CH2PR2 (R = Ph, Me, t-Bu) form the corresponding cyclometalated complexes when allowed to react with MCl2*2 Et2S (M = Pd, Pt).Under our reaction conditions they appear to be formed in the cis-form only.Mixed cyclometalated species are described as well as the behaviour of some cyclometalated compounds towards HCl, Br2 and HgBr2 and reactions with n-BuLi.The IR and NMR spectra of the prepared complexes are discussed.
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