Stereospecific Transannular Cyclization of (Z)- and (E)-Thiacyclooct-4-enes: Synthesis and Carbon-13 Nuclear Magnetic Resonance Spectra of Substituted cis-1-Thioniabicyclooctane Salts. Conformational Analysis (Force Field) of (E)-Thiacyclooct-4-ene

DOI: 10.1021/jo01301a020

Source and publish data:

Journal of Organic Chemistry p. 2641 - 2649 (1980)

Update date:2022-08-05

Topics:

Authors:

Calderoni, Carlo

Cere, Vanda

Pollicino, Salvatore

Sandri, Edda

Fava, Antonino

Guerra, Maurizio

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo01301a020

Several substituted (Z)- and (E)-thiacyclooct-4-enes (1-11) have been synthetized and their acid-promoted transannular cyclizations studied.The reaction appears to be stereospecific: thus the RR,SS and SR,RS diastereomers of 2-methyl-(E)-thiacyclooct-4-en

Full text of DOI:10.1021/jo01301a020

Products guided by the article

Product name:(Z)-1-(2-Phenylethyl)-Δ-4,5-thiocanium tetrafluoroborate

Cas No:73505-81-4

R&D Labs maybe for 73505-81-4

ShiJiaZhuang Dowell Chemical Co.,Ltd.

website:http://www.dowechem.com

Contact:+86-13463963265

Address:Xiyangling village, high tech Zone, Shijiazhuang，Hebei, China
C-LAB Chemievermittlung GmbH

Contact:+49-9398-993127

Address:Untertorstr. 27
Chengdu Aslee Biopharmaceuticals, Inc

Contact:18608018419

Address:Chengdu Aslee Biopharmaceuticals, Inc
Chengdu Chengnuo New-Tech Co., Ltd

Contact:0086-028-85749078

Address:4 Jiuyang road,Jiulong industrial port,Chengdu, China
Wansheng

Contact:86-21-31200601

Address:Room1618,FangzhengDaSha,No.1122 Xinjinqiao Road,Pudong New District,Shanghai ,China

Relevant to this article

Doi:10.1039/jr9510002761
(1951)
Heteroatomic derivatives of aziridine. 13. New macroheterocyclic compounds containing arylalkyl and functional groups attached to the endocyclic nitrogen atoms

Doi:10.1007/BF00505596
(1982)
A route to benzylic arylsulfoxides from β-ketosulfoxides

Doi:10.1016/j.tet.2016.05.038
(2016)
Preparation of 4-azaindole and 7-azaindole dimers with a bisalkoxyalkyl spacer in order to preferentially target melatonin MT₁ receptors over melatonin MT₂ receptors

Doi:10.1016/j.ejmech.2004.03.005
(2004)
TETRAZOLE DERIVATIVES. 24. 1- AND 2-METHYLTETRAZOLYL-CONTAINING TETRAZOLIUM SALTS. NATURE OF THE COLOR OF TETRAZOLIUM SALTS

Doi:10.1007/BF00475402
(1980)
Transesterification catalyzed by iron(III) β-diketonate species

Doi:10.1016/j.tet.2011.01.009
(2011)

Article Doi