Stereospecific Transannular Cyclization of (Z)- and (E)-Thiacyclooct-4-enes: Synthesis and Carbon-13 Nuclear Magnetic Resonance Spectra of Substituted cis-1-Thioniabicyclooctane Salts. Conformational Analysis (Force Field) of (E)-Thiacyclooct-4-ene

DOI: 10.1021/jo01301a020

Source and publish data:

Journal of Organic Chemistry p. 2641 - 2649 (1980)

Update date:2022-08-05

Topics:

Authors:

Calderoni, Carlo

Cere, Vanda

Pollicino, Salvatore

Sandri, Edda

Fava, Antonino

Guerra, Maurizio

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo01301a020

Several substituted (Z)- and (E)-thiacyclooct-4-enes (1-11) have been synthetized and their acid-promoted transannular cyclizations studied.The reaction appears to be stereospecific: thus the RR,SS and SR,RS diastereomers of 2-methyl-(E)-thiacyclooct-4-en

Full text of DOI:10.1021/jo01301a020

Products guided by the article

Product name:(Z)-1-(2-Phenylethyl)-Δ-4,5-thiocanium tetrafluoroborate

Cas No:73505-81-4

R&D Labs maybe for 73505-81-4

Anhui Xinyuan Technology Co.,Ltd

Contact:0086-559-3515800

Address:No.16 Zijin Rd, Circular Economic Zone, Huizhou District, Huangshan Anhui China
Shijiazhuang City Xiehe Pharmaceutical Co., Ltd

Contact:+86-311-80817929

Address:Shangzhuang,Shijiazhuang,China
Zha Yan

Contact:+86-13914766747

Address:Floors 21&22, Jin Cheng Tower, No. 216 Middle Longpan Road, Nanjing
suzhou chukai pharmateach co,.ltd

Contact:86-512-88812511

Address:Building 3, Wujiang Scientific Innovation Park, 2358 Changan Rd, Wujiang 215200, Jiangsu Province, P. R. China
SHIJIAZHUANG HENRYTE CHEMICALS CO,.LTD(expird)

Contact:+86-311-85208698 311-80837698

Address:NO.166, yuhua west road, SHIJIAZHUANG, China

Relevant to this article

Doi:10.1039/jr9510002761
(1951)
Heteroatomic derivatives of aziridine. 13. New macroheterocyclic compounds containing arylalkyl and functional groups attached to the endocyclic nitrogen atoms

Doi:10.1007/BF00505596
(1982)
A route to benzylic arylsulfoxides from β-ketosulfoxides

Doi:10.1016/j.tet.2016.05.038
(2016)
Preparation of 4-azaindole and 7-azaindole dimers with a bisalkoxyalkyl spacer in order to preferentially target melatonin MT₁ receptors over melatonin MT₂ receptors

Doi:10.1016/j.ejmech.2004.03.005
(2004)
TETRAZOLE DERIVATIVES. 24. 1- AND 2-METHYLTETRAZOLYL-CONTAINING TETRAZOLIUM SALTS. NATURE OF THE COLOR OF TETRAZOLIUM SALTS

Doi:10.1007/BF00475402
(1980)
Transesterification catalyzed by iron(III) β-diketonate species

Doi:10.1016/j.tet.2011.01.009
(2011)

Article Doi