Journal of Organic Chemistry p. 2273 - 2274 (1980)
Update date:2022-08-05
Topics:
Seyferth, Dietmar
Simon, Robert M.
Sepelak, Dennis J.
Klein, Helmut A.
The action of n-butyllithium in hexane on CF2BrCH=CH2/CF2=CHCH2Br (5:2 to 20:1 mixture) in 5:1:1 THF/Et2O/pentane at -95 deg C generates gem-difluoroallyllithium which may be trapped, generally in good yield, by an in situ procedure using triorganochlorosilanes (R3SiCF2CH=CH2) and aldehydes and ketones (RR'C(OH)CF2CH=CH2).
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Doi:10.1016/j.inoche.2003.11.013
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(1987)Doi:10.1007/BF00765603
(1980)Doi:10.1021/acs.jafc.5b02279
(2015)Doi:10.1248/cpb.27.3149
(1979)Doi:10.1021/jo01304a048
(1980)
