Journal of the Chemical Society, Dalton Transactions p. 447 - 453 (1980)
Update date:2022-08-02
Topics:
Favas, Mark C.
Kepert, David L.
Skelton, Brian W
White, Allan H.
The crystal structures of the title compounds, a=20.989(9), b=17.825(10), c=8.784(4) Angstroem, β=99.70(2) deg, and Z=4; those of (2) are monoclinic, space group P21/n, with a=15.181(7), b=18.799(4), c=12.053(4), β=106.62(3) deg, and Z=4.In both (1) and (2), the metal-central phosphorous distance is shorter <(1): 2.334(3), 2.328(4); (2): 2.479(2) Angstroem> than the metal-terminal phorous distances <(1): 2.355(4)-2.391(3); (2): 2.504(3), 2.532(3) Angstroem>.In (1) the mean Cr-C length is 1.84 Angstroem; in (2), the mean Mo-C-length is 1.97 Angstroem.
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Doi:10.1039/P29800001206
(1980)Doi:10.1016/S0040-4039(03)00224-7
(2003)Doi:10.1002/pola.24572
(2011)Doi:10.1016/S0040-4039(01)95424-3
(1979)Doi:10.1039/P29800000260
(1980)Doi:10.1021/ja961010w
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