Journal of Organic Chemistry p. 2736 - 2739 (1985)
Update date:2022-09-26
Topics:
Baum, Kurt
Tzeng, Dongjaw
Tetranitroethylene was isolated in 50 percent yield by flash vacuum pyrolysis of heksanitroethane.Critical for the isolation is a trap temperature such that dinitrogen tetraoxide is not condensed.Tetranitroethylene reacted quantitatively with anthracene to give 11,11,12,12,-tetranitro-9,10-dihydro-9,10-ethanoanthracene, and competition experiments with anthracene showed that tetranitroethylene is at least an order of magnitude more reactive than tetracyanoethylene.Tetranitroethylene reacted with cyclopentadiene to give 5,5,6,6-tetranitronorbornene and with ethanolto give ethyl dinitroacetate.Acetylenes and olefins reacted with tetranitroethylene to give 3-nitroisoxazoles and 3-nitro-2-isoxazolines, respectively.
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Doi:10.1007/BF00901733
(1964)Doi:10.1016/j.tetlet.2004.05.078
(2004)Doi:10.1016/0040-4039(81)80110-4
(1981)Doi:10.1002/zfch.19810210807
(1981)Doi:10.1039/P19830001765
(1983)Doi:10.1021/ja00272a012
(1986)