Tetrahedron Letters p. 1033 - 1036 (1981)
Update date:2022-08-05
Topics: Synthesis Yield Reaction (+/-)-Solavetivone (+/-)-Hinesol
Murai, Akio
Sato, Shingo
Masamune, Tadashi
A general efficient approach leading to the total synthesis of (+/-)-solavetivone, (+/-)-hinesol, and related spirovetivanes, is described.The process involves stereoselective formation of the asymmetric center at C-7 by ?-cyclisation as a key step.
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