
Chemistry Letters p. 145 - 148 (1980)
Update date:2022-08-03
Topics: Benzene Triplet Sensitized
Kitamura, Takashi
Toki, Susumu
Takamuku, Setsuo
Sakurai, Hiroshi
γ-Radiolysis of triphenylcyanocyclobutane (1) in benzene forms stilbene, cinnamonitrile and a stereo isomer of 1.The effect of additives and the kinetic treatment show that the cycloreversion of 1 proceeds by benzene triplet sensitization.Spectroscopic measurement in pulse radiolysis suggests the existence of 1,4-biradical as an intermediate.
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Doi:10.1016/S0022-328X(00)93819-1
(1980)Doi:10.1039/DT9800000712
(1980)Doi:10.1248/cpb.28.638
(1980)Doi:10.1039/b403200d
(2004)Doi:10.1016/S0040-4039(01)00228-3
(2001)Doi:10.1002/ardp.19803130305
(1980)