Journal of Organic Chemistry p. 3433 - 3436 (1980)
Update date:2022-08-04
Topics:
Taylor, Edward C.
Conley, Richard A.
Johnson, David K.
McKillop, Alexander
Ford, Michael E.
Treatment of chalcones (ArCH=CHCOAr') with thallium(III) trinitrate (TTN) in acidic methanol or in trimethyl orthoformate (TMOF) gives 3,3-dimethoxy-1,2-diarylpropan-1-ones (oxythallation, Ar rearrangement) and/or methyl 2,3-diaryl-3-methoxypropanoates (in situ ketal formation, oxythallation, Ar' rearrangement).The effect of substituents on Ar and Ar' on the ratio of the above rearrangement products has been examined.
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Doi:10.1021/jo00165a013
(1983)Doi:10.1016/S0039-128X(79)80008-2
(1979)Doi:10.1246/bcsj.56.2981
(1983)Doi:10.1007/BF00908224
(1962)Doi:10.1039/jr9630002256
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(1963)
