Journal of the Chemical Society. Perkin transactions II p. 668 - 671 (1980)
Update date:2022-08-05
Topics:
Lloyd, Douglas
Vincent, Colin A.
Walton, David J.
The 5,7-diphenyl-2,3-dihydro-1,4-diazepinium cation (II), dissolved in dimethylformamide, is reduced in two steps.The first wave, at -1.23 V with respect to an aqueous Ag-AgCl-KCl (saturated) reference, provides a radical which disproportionates to give the corresponding dihydrodiazepine base (I) and a tetrahydrodiazepine (IV).The second wave is at -2.00 V and produces the anion (IV).The reduction was studied by polarography, cyclic voltammetry, and preparative electrochemistry.The dihydrodiazepine base is electroinactive to -2.1 V, whereat it displays an apparently two-electron reduction wave.
View MoreAntaeus Bio-technology Co., LTD(expird)
Contact:021-31252569
Address:shanghai pudong
Liaoning Yufeng Chemical Co.,Ltd.
Contact:86-0419-3418888
Address:The metallurgical industrial zone,shoushan town, Liaoyang, Liaoning, China
Contact:86+21-56421993
Address:3F,BUILDING 10,NO.2889 JINKE ROAD, SHANGHAI.
Shao Xing Empire Import&Export CO.,ltd
Contact:86-575-82127757
Address:11#, Weiwu Road, Shangyu Industrial Park, Hangzhou Bay, Hangzhou, Zhejiang Province, China
TIANJIN DONGRUXIANG MINERALS MARKETING CO.,LTD(expird)
Contact:22-58516360
Address:tianjin
Doi:10.1021/jm049939b
(2004)Doi:10.1007/BF00777380
(1980)Doi:10.1016/j.jorganchem.2004.04.021
(2004)Doi:10.1021/ja00529a058
(1980)Doi:10.1021/ja00530a020
(1980)Doi:10.1081/NCN-200051900
(2005)
