SULFUR PARTICIPATION IN SOLVOLYSIS INVOLVING FOUR-MEMBERED RING INTERMEDIATES

DOI: 10.1016/S0040-4039(01)85465-4

Source and publish data:

Tetrahedron Letters p. 331 - 334 (1980)

Update date:2022-08-04

Topics:

Authors:

Eliel, Ernest L.

Pearson, William H.

Jewell, Linda M.

Abatjoglou, Anthony C.

Kenan, William R.

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Article abstract of DOI:10.1016/S0040-4039(01)85465-4

Neighboring group participation via four-membered ring intermediates resulting in complete rearrangement occurs in the methanolysis of R1R2C(SCH2C6H5)CH2CH(R3)OTs when R1=R2=R3=Me and when R1=R2=Me, R3=H.No rearrangement is found for R1=R2=R3=H or R1=R2=H, R3=Me.The case of R1=Me, R2=R3=H is intermediate.

Full text of DOI:10.1016/S0040-4039(01)85465-4

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