Controlled Reduction of Pyrimidin(e)-2(1H)-ones and -thiones with Metal Hydride Complexes. Regioselective Preparation of Dihydro- and Tetrahydro-pyrimidin-2(1H)-ones and the Corresponding Thiones

DOI: 10.1039/P19810001622

Source and publish data:

Journal of the Chemical Society. Perkin transactions I p. 1622 - 1625 (1981)

Update date:2022-08-02

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Authors:

Kashima, Choji

Katoh, Akira

Yokota, Yuko

Omote, Yoshimori

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Article abstract of DOI:10.1039/P19810001622

1,4,6-Trisubstituted pyrimidin-2(1H)-ones were easily reduced with sodium borohydride to give mixtures of 3-aryl-3,4-dihydro-, 1-aryl-3,4-dihydro-, and 3,4,5,6-tetrahydro-pyrimidin-2(1H)-ones.The ratio of the three products was dramatically dependent on t

Full text of DOI:10.1039/P19810001622

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