Controlled Reduction of Pyrimidin(e)-2(1H)-ones and -thiones with Metal Hydride Complexes. Regioselective Preparation of Dihydro- and Tetrahydro-pyrimidin-2(1H)-ones and the Corresponding Thiones

DOI: 10.1039/P19810001622

Source and publish data:

Journal of the Chemical Society. Perkin transactions I p. 1622 - 1625 (1981)

Update date:2022-08-02

Topics:

Authors:

Kashima, Choji

Katoh, Akira

Yokota, Yuko

Omote, Yoshimori

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/P19810001622

1,4,6-Trisubstituted pyrimidin-2(1H)-ones were easily reduced with sodium borohydride to give mixtures of 3-aryl-3,4-dihydro-, 1-aryl-3,4-dihydro-, and 3,4,5,6-tetrahydro-pyrimidin-2(1H)-ones.The ratio of the three products was dramatically dependent on t

Full text of DOI:10.1039/P19810001622

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:1-(p-chlorophenyl)-3,4,5,6-tetrahydro-4,6-dimethylpyrimidin-2(1H)-one

Cas No:74360-04-6

R&D Labs maybe for 74360-04-6

Beijing Tianjia Chemical Science & Technology Co.,Ltd

Contact:86-0550-2392698

Address:No.388, Shiliang Road (East),
Wuhan Better Organic Technology Inc.

Contact:13307163183

Address:Wuhan Economic&Technology Development Zone, Hubei
Chameleon Specialty Chemicals

Contact:+44 7958 511245

Address:PO Box 469, Manchester, UK
Taizhou Chemedir Biopharm-tech Co., Ltd

Contact:+86 523 86200218

Address:G09, No. 1 Avenue China Medical City, Taizhou,Jiangsu, China
PharmaResources(Kaiyuan)CO,.Ltd

Contact:+86-21-50720028

Address:No.3, Beihuan Road, Economic Development District, Kaiyuan City, Tieling City, Liaoning Province, China 112300

Relevant to this article

Regiospecific synthesis of 3,5-bis(bromomethyl)benzoic acid, a cysteine crosslinking agent

Doi:10.1016/S0040-4020(01)81898-6
(1993)
Gold(I)/(III)-catalyzed rearrangement of divinyl ketones and acyloxyalkynyloxiranes into cyclopentenones

Doi:10.1021/ol403663j
(2014)
Synthesis and characterisation of novel o-xylene-based P,E ligands

Doi:10.1039/c3ob42244e
(2014)
When does a Nitrogen attached to a λ³-Phosphorus assume a Pyramidal Geometry? Crystal Structures of Group 6 Metal Carbonyl Complexes of Isometric Forms of λ³-Cyclotriphosphazanes

Doi:10.1039/DT9930003635
(1993)
MIL-53(Fe): Introduction of a new catalyst for the synthesis of Pyrimido[4,5-d]pyrimidine derivatives under solvent-free conditions

Doi:10.1016/j.molstruc.2019.07.065
(2019)
Solvent-free peptide synthesis assisted by microwave irradiation: Environmentally benign synthesis of bioactive peptides

Doi:10.1039/c3ra46643d
(2014)

Article Doi