THE USE OF METALLOIDS (-SiMe3,-SnR3) AS PROTECTED CARBANIONS; SELECTIVE ACTIVATION AND NEW CYCLIZATION PROCESSES

DOI: 10.1016/S0040-4020(01)93282-X

Source and publish data:

Tetrahedron p. 4069 - 4079 (1981)

Update date:2022-08-05

Topics:

Authors:

Andarsen, Niels H.

McCrae, David A.

Grotjahn, Douglas B.

Gabhe, Satish Y.

Theodore, Louis J.

et al. et al.

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Article abstract of DOI:10.1016/S0040-4020(01)93282-X

Two aspects of organosilicon and -tin chemistry will be dealt with in this paper: the reactivity of allylmetalloids and the potential of the C-MR₃ function as a protected carbanion which can be unmasked to provide synthetically useful carbon nucleophiles with the primary focus on the latter.

Full text of DOI:10.1016/S0040-4020(01)93282-X

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