Tetrahedron p. 1435 - 1446 (1991)
Update date:2022-07-29
Topics:
Sutowardoyo, Kun I.
Emziane, Mohamed
Lhoste, Paul
Sinou, Denis
The ring-opening of functionalized epoxides with trimethylsilyl azide in the presence of a catalytic amount of Ti(O-i-Pr)4 or Al(O-i-Pr)3 is described.The reaction is stereospecific and highly regiospecific, leading generally to the formation of the carbon-azido bond on the less substituted carbon.The mechanism of this reaction is also discussed.
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Doi:10.1021/ja00906a029
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