Tetrahedron Letters p. 2695 - 2698 (1981)
Update date:2022-07-29
Topics:
Kashman, Y.
Rudi, A.
The RPX2.AlX3 complex (1) reacts with unsaturated ketones and imines to give novel 7-oxa and 7-aza-2-phosphabicyclo<2.2.1>heptanes (compounds 3 and 6 respectively).A new 1,3-dipolar addition of (CH3)2CCH2PXR to Ar-N=C=S was disclosed resulting in the formation of the 2-imino-1,3-thiaphospholanes (7).
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